| Juan Carlos Holgado | Archery Team, Men (Olympic) | Archery |
| Antonio Vázquez | Archery Team, Men (Olympic) | Archery |
| Alfonso Menéndez | Archery Team, Men (Olympic) | Archery |
| Fermín Cacho | Athletics 1,500 metres, Men (Olympic) | Athletics |
| Daniel Plaza | Athletics 20 kilometres Race Walk, Men (Olympic) | Athletics |
| José Moreno | Cycling Track (Cycling) 1,000 metres Time Trial, Men (Olympic) | Cycling Track (Cycling) |
| Miguel Hernández | Football (Football) Football, Men (Olympic) | Football (Football) |
| Roberto Solozábal | Football (Football) Football, Men (Olympic) | Football (Football) |
| Paco Soler | Football (Football) Football, Men (Olympic) | Football (Football) |
| Pinilla | Football (Football) Football, Men (Olympic) | Football (Football) |
| Alfonso | Football (Football) Football, Men (Olympic) | Football (Football) |
| Kiko | Football (Football) Football, Men (Olympic) | Football (Football) |
| Luis Enrique | Football (Football) Football, Men (Olympic) | Football (Football) |
| Juanma López | Football (Football) Football, Men (Olympic) | Football (Football) |
| Lasa | Football (Football) Football, Men (Olympic) | Football (Football) |
| Toni | Football (Football) Football, Men (Olympic) | Football (Football) |
| Gabriel Vidal | Football (Football) Football, Men (Olympic) | Football (Football) |
| Pep Guardiola | Football (Football) Football, Men (Olympic) | Football (Football) |
| Albert Ferrer | Football (Football) Football, Men (Olympic) | Football (Football) |
| Abelardo | Football (Football) Football, Men (Olympic) | Football (Football) |
| Rafa Berges | Football (Football) Football, Men (Olympic) | Football (Football) |
| José Emilio Amavisca | Football (Football) Football, Men (Olympic) | Football (Football) |
| David Villabona | Football (Football) Football, Men (Olympic) | Football (Football) |
| Núria Olivé | Hockey Hockey, Women (Olympic) | Hockey |
| Maribel Martínez | Hockey Hockey, Women (Olympic) | Hockey |
| Carmen Barea | Hockey Hockey, Women (Olympic) | Hockey |
| Sonia Barrio | Hockey Hockey, Women (Olympic) | Hockey |
| Mercedes Coghen | Hockey Hockey, Women (Olympic) | Hockey |
| Natalia Dorado | Hockey Hockey, Women (Olympic) | Hockey |
| Nagore Gabellanes | Hockey Hockey, Women (Olympic) | Hockey |
| Mariví González | Hockey Hockey, Women (Olympic) | Hockey |
| Anna Maiques | Hockey Hockey, Women (Olympic) | Hockey |
| Silvia Manrique | Hockey Hockey, Women (Olympic) | Hockey |
| Eli Maragall | Hockey Hockey, Women (Olympic) | Hockey |
| Teresa Motos | Hockey Hockey, Women (Olympic) | Hockey |
| Virginia Ramírez | Hockey Hockey, Women (Olympic) | Hockey |
| Masa Rodríguez | Hockey Hockey, Women (Olympic) | Hockey |
| Maider Tellería | Hockey Hockey, Women (Olympic) | Hockey |
| Almudena Muñoz | Judo Half-Lightweight, Women (Olympic) | Judo |
| Míriam Blasco | Judo Lightweight, Women (Olympic) | Judo |
| José María van der Ploeg | Sailing One Person Dinghy, Men (Olympic) | Sailing |
| Kiko Sánchez | Sailing Two Person Dinghy, Men (Olympic) | Sailing |
| Jordi Calafat | Sailing Two Person Dinghy, Men (Olympic) | Sailing |
| Patricia Guerra | Sailing Two Person Dinghy, Women (Olympic) | Sailing |
| Theresa Zabell | Sailing Two Person Dinghy, Women (Olympic) | Sailing |
| Domingo Manrique | Sailing Two Person Heavyweight Dinghy, Open (Olympic) | Sailing |
| Luis Doreste | Sailing Two Person Heavyweight Dinghy, Open (Olympic) | Sailing |
| Martín López-Zubero | Swimming (Aquatics) 200 metres Backstroke, Men (Olympic) | Swimming (Aquatics) |
| Antonio Peñalver | Athletics Decathlon, Men (Olympic) | Athletics |
| Faustino Reyes | Boxing Featherweight, Men (Olympic) | Boxing |
| Carolina Pascual | Rhythmic Gymnastics (Gymnastics) Individual, Women (Olympic) | Rhythmic Gymnastics (Gymnastics) |
| Natalia Vía Dufresne | Sailing One Person Dinghy, Women (Olympic) | Sailing |
| Conchita Martínez | Tennis Doubles, Women (Olympic) | Tennis |
| Arantxa Sánchez Vicario | Tennis Doubles, Women (Olympic) | Tennis |
| Jordi Arrese | Tennis Singles, Men (Olympic) | Tennis |
| Rubén Michavila | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Marco Antonio González | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Jesús Miguel Rollán | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Ricardo Sánchez | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Jordi Sans | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Josep Picó | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Sergio Pedrerol | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Miki Oca | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Daniel Ballart | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Manuel Estiarte | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Pedro García | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Salvador Gómez | Water Polo (Aquatics) Water Polo, Men (Olympic) | Water Polo (Aquatics) |
| Javier García | Athletics Pole Vault, Men (Olympic) | Athletics |
| Arantxa Sánchez Vicario | Tennis Singles, Women (Olympic) | Tennis |