| Gervasio Deferr | Artistic Gymnastics (Gymnastics) Horse Vault, Men (Olympic) | Artistic Gymnastics (Gymnastics) |
| David Cal | Canoe Sprint (Canoeing) Canadian Singles, 1,000 metres, Men (Olympic) | Canoe Sprint (Canoeing) |
| Xabier Fernández | Sailing Skiff, Open (Olympic) | Sailing |
| Iker Martínez | Sailing Skiff, Open (Olympic) | Sailing |
| Francisco Javier Fernández | Athletics 20 kilometres Race Walk, Men (Olympic) | Athletics |
| Pablo Herrera | Beach Volleyball (Volleyball) Beach Volleyball, Men (Olympic) | Beach Volleyball (Volleyball) |
| Javier Bosma | Beach Volleyball (Volleyball) Beach Volleyball, Men (Olympic) | Beach Volleyball (Volleyball) |
| David Cal | Canoe Sprint (Canoeing) Canadian Singles, 500 metres, Men (Olympic) | Canoe Sprint (Canoeing) |
| José Antonio Hermida | Cycling Mountain Bike (Cycling) Cross-Country, Men (Olympic) | Cycling Mountain Bike (Cycling) |
| José Antonio Escuredo | Cycling Track (Cycling) Keirin, Men (Olympic) | Cycling Track (Cycling) |
| Joan Llaneras | Cycling Track (Cycling) Points Race, Men (Olympic) | Cycling Track (Cycling) |
| Juan Antonio Jiménez | Equestrian Dressage (Equestrian) Team, Open (Olympic) | Equestrian Dressage (Equestrian) |
| Rafael Soto | Equestrian Dressage (Equestrian) Team, Open (Olympic) | Equestrian Dressage (Equestrian) |
| Beatriz Ferrer-Salat Serra | Equestrian Dressage (Equestrian) Team, Open (Olympic) | Equestrian Dressage (Equestrian) |
| Ignacio Rambla | Equestrian Dressage (Equestrian) Team, Open (Olympic) | Equestrian Dressage (Equestrian) |
| Rafael Trujillo | Sailing One Person Dinghy, Men (Olympic) | Sailing |
| Sandra Azón | Sailing Two Person Dinghy, Women (Olympic) | Sailing |
| Natalia Vía Dufresne | Sailing Two Person Dinghy, Women (Olympic) | Sailing |
| María Quintanal | Shooting Trap, Women (Olympic) | Shooting |
| Conchita Martínez | Tennis Doubles, Women (Olympic) | Tennis |
| Vivi Ruano | Tennis Doubles, Women (Olympic) | Tennis |
| Patricia Moreno | Artistic Gymnastics (Gymnastics) Floor Exercise, Women (Olympic) | Artistic Gymnastics (Gymnastics) |
| Joan Lino Martínez | Athletics Long Jump, Men (Olympic) | Athletics |
| Manuel Martínez | Athletics Shot Put, Men (Olympic) | Athletics |
| Sergi Escobar | Cycling Track (Cycling) Individual Pursuit, 4,000 metres, Men (Olympic) | Cycling Track (Cycling) |
| Asier Maeztu | Cycling Track (Cycling) Team Pursuit, 4,000 metres, Men (Olympic) | Cycling Track (Cycling) |
| Carlos Castaño | Cycling Track (Cycling) Team Pursuit, 4,000 metres, Men (Olympic) | Cycling Track (Cycling) |
| Sergi Escobar | Cycling Track (Cycling) Team Pursuit, 4,000 metres, Men (Olympic) | Cycling Track (Cycling) |
| Carlos Torrent | Cycling Track (Cycling) Team Pursuit, 4,000 metres, Men (Olympic) | Cycling Track (Cycling) |
| Beatriz Ferrer-Salat Serra | Equestrian Dressage (Equestrian) Individual, Open (Olympic) | Equestrian Dressage (Equestrian) |