| 13th | Rui Silva | Athletics 1,500 metres, Men (Olympic) |
| 10th | Carla Sacramento | Athletics 1,500 metres, Women (Olympic) |
| 14th | José Ramos | Athletics 10,000 metres, Men (Olympic) |
| 3rd | Fernanda Ribeiro | Athletics 10,000 metres, Women (Olympic) |
| 12th | Ana Dias | Athletics 10,000 metres, Women (Olympic) |
| - | João Vieira | Athletics 20 kilometres Race Walk, Men (Olympic) |
| 14th | Susana Feitor | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 13th | Manuel Silva | Athletics 3,000 metres Steeplechase, Men (Olympic) |
| 7th | Pedro Rodrigues | Athletics 400 metres Hurdles, Men (Olympic) |
| 17th | Hélder Ornelas | Athletics 5,000 metres, Men (Olympic) |
| 33rd | Pedro Martins | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 5th | João Pires | Athletics 800 metres, Men (Olympic) |
| 12th | Mário Aníbal | Athletics Decathlon, Men (Olympic) |
| 11th | Teresa Machado | Athletics Discus Throw, Women (Olympic) |
| 37th | Vítor Costa | Athletics Hammer Throw, Men (Olympic) |
| 10th | Carlos Calado | Athletics Long Jump, Men (Olympic) |
| 50th | Luís Novo | Athletics Marathon, Men (Olympic) |
| 11th | António Pinto | Athletics Marathon, Men (Olympic) |
| 18th | Domingos Castro | Athletics Marathon, Men (Olympic) |
| 21st | Manuela Machado | Athletics Marathon, Women (Olympic) |
| 29th | João André | Athletics Pole Vault, Men (Olympic) |
| 32nd | Nuno Fernandes | Athletics Pole Vault, Men (Olympic) |