| 34th | Rui Pedro Silva | Athletics 10,000 metres, Men (Olympic) |
| 45th | Sérgio Vieira | Athletics 20 kilometres Race Walk, Men (Olympic) |
| 32nd | João Vieira | Athletics 20 kilometres Race Walk, Men (Olympic) |
| - | Susana Feitor | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 9th | Vera Santos | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 8th | Ana Cabecinha | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 8th | Arnaldo Abrantes | Athletics 200 metres, Men (Olympic) |
| 11th | Alberto Paulo | Athletics 3,000 metres Steeplechase, Men (Olympic) |
| 15th | Clarisse Cruz | Athletics 3,000 metres Steeplechase, Women (Olympic) |
| 9th | Sara Moreira | Athletics 3,000 metres Steeplechase, Women (Olympic) |
| 5th | Jéssica Augusto | Athletics 3,000 metres Steeplechase, Women (Olympic) |
| 6th | Edivaldo Monteiro | Athletics 400 metres Hurdles, Men (Olympic) |
| 14th | Jéssica Augusto | Athletics 5,000 metres, Women (Olympic) |
| 11th | António Pereira | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 40th | Augusto Cardoso | Athletics 50 kilometres Race Walk, Men (Olympic) |
| - | João Vieira | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 6th | Carmo Tavares | Athletics 800 metres, Women (Olympic) |
| 44th | Vânia Silva | Athletics Hammer Throw, Women (Olympic) |
| 23rd | Sílvia Cruz | Athletics Javelin Throw, Women (Olympic) |
| 30th | Paulo Gomes | Athletics Marathon, Men (Olympic) |
| 46th | Hélder Ornelas | Athletics Marathon, Men (Olympic) |
| 46th | Ana Dias | Athletics Marathon, Women (Olympic) |
| 32nd | Marisa Barros | Athletics Marathon, Women (Olympic) |
| - | Inês Monteiro | Athletics Marathon, Women (Olympic) |
| =19th | Sandra Tavares | Athletics Pole Vault, Women (Olympic) |
| 35th | Marco Fortes | Athletics Shot Put, Men (Olympic) |
| 1st | Nelson Évora | Athletics Triple Jump, Men (Olympic) |