| 12th | Marta Pen Freitas | Athletics 1,500 metres, Women (Olympic) |
| 26th | Carla Salomé Rocha | Athletics 10,000 metres, Women (Olympic) |
| 53rd | Sérgio Vieira | Athletics 20 kilometres Race Walk, Men (Olympic) |
| 31st | João Vieira | Athletics 20 kilometres Race Walk, Men (Olympic) |
| 12th | Inês Henriques | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 37th | Daniela Cardoso | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 6th | Ana Cabecinha | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 6th | Vera Barbosa | Athletics 400 metres Hurdles, Women (Olympic) |
| 4th | Cátia Azevedo | Athletics 400 metres, Women (Olympic) |
| 36th | Miguel Carvalho | Athletics 50 kilometres Race Walk, Men (Olympic) |
| - | João Vieira | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 32nd | Pedro Isidro | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 122nd | Rui Pedro Silva | Athletics Marathon, Men (Olympic) |
| 133rd | Ricardo Ribas | Athletics Marathon, Men (Olympic) |
| 16th | Dulce Félix | Athletics Marathon, Women (Olympic) |
| - | Jéssica Augusto | Athletics Marathon, Women (Olympic) |
| - | Sara Moreira | Athletics Marathon, Women (Olympic) |
| =29th | Maria Eleonor Tavares | Athletics Pole Vault, Women (Olympic) |
| =24th | Marta Onofre | Athletics Pole Vault, Women (Olympic) |
| 29th | Tsanko Arnaudov | Athletics Shot Put, Men (Olympic) |
| 6th | Nelson Évora | Athletics Triple Jump, Men (Olympic) |
| 6th | Patrícia Mamona | Athletics Triple Jump, Women (Olympic) |
| 9th | Susana Costa | Athletics Triple Jump, Women (Olympic) |