| - | Anzhelika Shevchenko | Athletics 1,500 metres, Women (Olympic) |
| - | Hanna Mishchenko | Athletics 1,500 metres, Women (Olympic) |
| 26th | Mykola Labovskyi | Athletics 10,000 metres, Men (Olympic) |
| 19th | Olha Skrypak | Athletics 10,000 metres, Women (Olympic) |
| 5th | Nataliya Pohrebniak | Athletics 100 metres, Women (Olympic) |
| 5th | Olesia Povkh | Athletics 100 metres, Women (Olympic) |
| 29th | Ruslan Dmytrenko | Athletics 20 kilometres Race Walk, Men (Olympic) |
| 45th | Ivan Losev | Athletics 20 kilometres Race Walk, Men (Olympic) |
| - | Nazar Kovalenko | Athletics 20 kilometres Race Walk, Men (Olympic) |
| - | Olena Shumkina | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 13th | Nadiya Prokopuk-Borovska | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 24th | Olha Yakovenko | Athletics 20 kilometres Race Walk, Women (Olympic) |
| 4th | Serhiy Smelyk | Athletics 200 metres, Men (Olympic) |
| 4th | Yelyzaveta Bryzhina | Athletics 200 metres, Women (Olympic) |
| 4th | Khrystyna Stuy | Athletics 200 metres, Women (Olympic) |
| 4th | Mariya Riemien | Athletics 200 metres, Women (Olympic) |
| 8th | Vadym Slobodeniuk | Athletics 3,000 metres Steeplechase, Men (Olympic) |
| 6th | Valentyna Horpynych-Zhudina | Athletics 3,000 metres Steeplechase, Women (Olympic) |
| - | Svitlana Shmidt | Athletics 3,000 metres Steeplechase, Women (Olympic) |
| 3rd | Khrystyna Stuy | Athletics 4 × 100 metres Relay, Women (Olympic) |
| 3rd | Yelyzaveta Bryzhina | Athletics 4 × 100 metres Relay, Women (Olympic) |
| 3rd | Mariya Riemien | Athletics 4 × 100 metres Relay, Women (Olympic) |
| 3rd | Olesia Povkh | Athletics 4 × 100 metres Relay, Women (Olympic) |
| 3rd | Hanna Yaroshchuk-Ryzhkova | Athletics 4 × 400 metres Relay, Women (Olympic) |
| 3rd | Alina Lohvynenko | Athletics 4 × 400 metres Relay, Women (Olympic) |
| 3rd | Nataliya Pyhyda | Athletics 4 × 400 metres Relay, Women (Olympic) |
| 3rd | Olha Zemliak | Athletics 4 × 400 metres Relay, Women (Olympic) |
| 6th | Stanislav Melnykov | Athletics 400 metres Hurdles, Men (Olympic) |
| - | Hanna Titimets | Athletics 400 metres Hurdles, Women (Olympic) |
| 4th | Hanna Yaroshchuk-Ryzhkova | Athletics 400 metres Hurdles, Women (Olympic) |
| 4th | Vitaliy Butrym | Athletics 400 metres, Men (Olympic) |
| 4th | Nataliya Pyhyda | Athletics 400 metres, Women (Olympic) |
| 6th | Alina Lohvynenko | Athletics 400 metres, Women (Olympic) |
| 17th | Serhiy Lebid | Athletics 5,000 metres, Men (Olympic) |
| - | Liudmyla Kovalenko | Athletics 5,000 metres, Women (Olympic) |
| 32nd | Serhiy Budza | Athletics 50 kilometres Race Walk, Men (Olympic) |
| - | Oleksiy Kazanin | Athletics 50 kilometres Race Walk, Men (Olympic) |
| 16th | Ihor Hlavan | Athletics 50 kilometres Race Walk, Men (Olympic) |
| - | Yuliya Krevsun | Athletics 800 metres, Women (Olympic) |
| 5th | Nataliya Lupu | Athletics 800 metres, Women (Olympic) |
| 7th | Oleksiy Kasianov | Athletics Decathlon, Men (Olympic) |
| 33rd | Mykyta Nesterenko | Athletics Discus Throw, Men (Olympic) |
| 26th | Kateryna Karsak | Athletics Discus Throw, Women (Olympic) |
| 17th | Nataliya Fokina-Semenova | Athletics Discus Throw, Women (Olympic) |
| 4th | Oleksiy Sokyrskyi | Athletics Hammer Throw, Men (Olympic) |
| - | Oleksandr Dryhol | Athletics Hammer Throw, Men (Olympic) |
| NM | Artem Rubanko | Athletics Hammer Throw, Men (Olympic) |
| 27th | Iryna Novozhylova | Athletics Hammer Throw, Women (Olympic) |
| - | Liudmyla Yosypenko | Athletics Heptathlon, Women (Olympic) |
| 8th | Hanna Melnychenko-Kasianova | Athletics Heptathlon, Women (Olympic) |
| - | Nataliya Dobrynska | Athletics Heptathlon, Women (Olympic) |
| =8th | Andriy Protsenko | Athletics High Jump, Men (Olympic) |
| =15th | Dmytro Dem'ianiuk | Athletics High Jump, Men (Olympic) |
| 6th | Bohdan Bondarenko | Athletics High Jump, Men (Olympic) |
| =14th | Olena Kholosha | Athletics High Jump, Women (Olympic) |
| 33rd | Vita Stopina | Athletics High Jump, Women (Olympic) |
| - | Oleksandr P'iatnytsia | Athletics Javelin Throw, Men (Olympic) |
| 13th | Roman Avramenko | Athletics Javelin Throw, Men (Olympic) |
| 17th | Vira Rebryk | Athletics Javelin Throw, Women (Olympic) |
| 20th | Hanna Hatsko-Fedusova | Athletics Javelin Throw, Women (Olympic) |
| 26th | Marharyta Dorozhon | Athletics Javelin Throw, Women (Olympic) |
| 31st | Viktor Kuznietsov | Athletics Long Jump, Men (Olympic) |
| 16th | Vita Rybalko | Athletics Long Jump, Women (Olympic) |
| - | Marharyta Tverdokhlib | Athletics Long Jump, Women (Olympic) |
| 59th | Ivan Babaryka | Athletics Marathon, Men (Olympic) |
| 29th | Vitaliy Shafar | Athletics Marathon, Men (Olympic) |
| 12th | Oleksandr Sitkovskyi | Athletics Marathon, Men (Olympic) |
| 47th | Olena Burkovska | Athletics Marathon, Women (Olympic) |
| - | Tetiana Hamera-Shmyrko | Athletics Marathon, Women (Olympic) |
| - | Tetiana Filoniuk | Athletics Marathon, Women (Olympic) |
| - | Maksym Mazuryk | Athletics Pole Vault, Men (Olympic) |
| NH | Denys Yurchenko | Athletics Pole Vault, Men (Olympic) |
| =32nd | Hanna Shelekh | Athletics Pole Vault, Women (Olympic) |
| =25th | Nataliya Kushch-Mazuryk | Athletics Pole Vault, Women (Olympic) |
| - | Andriy Semenov | Athletics Shot Put, Men (Olympic) |
| 3rd | Olha Saladukha | Athletics Triple Jump, Women (Olympic) |
| 15th | Hanna Demydova | Athletics Triple Jump, Women (Olympic) |